研究業績-中野研究室

研究業績publications

原著論文

(59) The Synthesis and Properties of Ladder-Type π-Conjugated Compounds with Pyrrole and Phosphole Rings
Truong, M. A.; Morishita, S.; Noguchi, K.; Nakano, K.
Molecules 2024, 29, 38.(doi)

　　　　　　
(58) Furan-Containing Chiral Spiro-Fused Polycyclic Aromatic Compounds: Synthesis and Photophysical Properties
Nakano, K.; Takase, K.; Noguchi, K.
Molecules 2022, 27, 5103.(doi)
(57) Transformation of Thia[7]helicene to Aza[7]helicenes and [7]Helicene-like Compounds via Aromatic Metamorphosis
Uematsu, K.; Hayasaka, C.; Takase, K.; Noguchi, K.; Nakano, K.
Molecules 2022, 27, 606.(doi)
(56) Dibenzo[d,d']benzo[2,1-b:3,4-b']difurans with extended p-conjugated chains: synthetic approaches and properties
Hirano, M.; Okada, H.; Hayasaka, C.; Komine, N.; Kiyota, S.; Nakano, K.
New J. Chem. 2022, 46, 1003. (doi)
(55) Synthesis of π-Extended Oxacenes and Their Application to Organic Field-Effect Transistors
Hayasaka, C.; Nagano, S.; Nakano, K.
Org. Electron. 2022, 100, 106335. (doi)

　　　　　
(54) Synthesis and Properties of Spiro-double Sila[7]helicene: The LUMO Spiro-conjugation
Terada, N.; Umematsu, K.; Higuchi, R.; Tokimaru, Y.; Sato, Y.; Nakano, K.; Nozaki, K
Chem. Eur. J. 2021, 27, 9342-9349. (doi)
(53) Chiral Benzo[b]silole-Fused 9,9'-Spirobi[fluorene]: Synthesis, Chiroptical Properties, and Transformation to Π-Extended Polycyclic Arene
Kubo, M.; Noguchi, K.; Nakano, K.
ChemPlusChem 2021, 86, 171-175. (doi)
(52) Aromatic Metamorphosis of Thiophenes by Means of Desulfurative Dilithiation
Kaga, A.; Iida, H.; Tsuchiya, S.; Saito, H.; Nakano, K.; Yorimitsu, H.
Chem. Eur. J. 2021, 27, 4567-4572. (doi)
Highlighted in Synfacts
(51) Polycarbonate-block-polycycloalkenes via epoxide/carbon dioxide copolymerization and ring-opening metathesis polymerization
Nakabayshi, Y.; Nakano, K.
Polym. J. 2021, 53, 203-208. (doi)
(50) Solvent-sensitive Circularly Polarized Luminescent Compounds Bearing a 9,9'-Spirobi[fluorene] Skeleton
Kubo, M.; Takase, K.; Noguchi, K.; Nakano, K.
Org. Biomol. Chem. 2020, 18, 2866-2876. (doi)
(49) Random Copolymers of Ethylene Carbonate and Ethylene Oxide for Li-Ion Conductive Solid Electrolytes
Tominaga, Y.; Nakano, K.; Morioka, T.
Electrochim. Acta 2019, 312, 343-348. (doi)
(48) Dinuclear Co-Salcy Complexes with A Dibenzofuran Linker for Copolymerizations of Epoxides with Cyclic Anhydrides or Carbon Dioxide
Hiranoi, Y.; Nakano, K.
Chem. Lett. 2019, 48, 479-482. (doi)
(47) Synthesis of Pyrrole-Containing Chiral Spiro Molecules and Their Optical and Chiroptical Properties
Takase, K.; Noguchi, K.; Nakano, K.
Bull. Chem. Soc. Jpn. 2019, 92, 1008-1017. (doi)
(46) [1]Benzothiophene-Fused Chiral Spiro Polycyclic Aromatic Compounds: Optical Resolution, Functionalization, and Optical Properties
Takase, K.; Noguchi, K.; Nakano, K.
J. Org. Chem. 2018, 83, 15057-15065. (doi)

　　　　　　
(45) Copolymerization of Epoxides with Cyclic Anhydrides Catalyzed by Dinuclear Cobalt Complexes
Hiranoi Y.; Nakano, K.
Beilstein J. Org. Chem. 2018, 14, 2779-2788. (doi)
(44) Block Copolymers of Aliphatic Polycarbonates: Combination of Immortal Epoxide/Carbon-dioxide Copolymerization and Atom Transfer Radical Polymerization of Vinyl Monomers
Mizuno Y.; Nakano, K.
Chem. Lett. 2018, 47, 580-583. (doi)
(43) Synthesis and Properties of [7]Helicene and [7]Helicene-like Compounds with a Cyclopenta[1,2-b:4,3-b']dithiophene or Dithieno[2,3-b:3',2'-d]heterole Skeleton
Uematsu K.; Noguchi, K.; Nakano, K.
Phys. Chem. Chem. Phys. 2018, 20, 3286-3295. (doi)
(42) Circularly Polarized Luminescence from Chiral Spiro Molecules: Synthesis and Optical Properties of 10,10'-Spirobi(indeno[1,2-b][1]benzothiophene) Derivatives
Takase K.; Noguchi, K.; Nakano, K.
Org. Lett. 2017, 19, 5082-5085. (doi)
(41) Multinuclear Cobalt-salen Complexes with Phenylene Linker for Epoxide Polymerizations
Hiranoi, Y.; Hatanaka, M.; Nakano, K.
J. Polym. Sci. Part A: Polym. Chem. 2017, 55, 2150-2159. (doi)
(40) Ion-conductive Properties of a Polymer Electrolyte Based on Ethylene Carbonate/Ethylene Oxide Random Copolymer
Morioka, T.; Nakano, K.; Tominaga, Y.
Macromol. Rapid Commun. 2017, 38, 1600652. (doi)
(39) Synthesis and Properties of [7]Helicene-like Compounds Fused with a Fluorene Unit
Oyama, H.; Akiyama, M.; Nakano, K.; Naito, M.; Nobusawa, K.; Nozaki, K.
Org. Lett. 2016, 18, 3654-3657. (doi)
(38) Syntheses and Properties of Ladder-type π-Conjugated Compounds Containing a Benzo[2,1-b:3,4-b']dithiophene Skeleton
Truong, M. A.; Nakano, K.
Bull. Chem. Soc. Jpn. 2016, 89, 1034-1040. (doi)
(37) Syntheses of Dibenzo[d,d']benzo[2,1-b:3,4-b']difuran Derivatives and Their Application to Organic Field-effect Transistors
Truong, M. A.; Nakano, K.
Beilstein J. Org. Chem. 2016, 12, 805-812. (doi)
(36) Pyrazole Supported Zinc(II) Benzoates as Catalysts for the Ring Opening Copolymerization of Cyclohexene Oxide and Carbon Dioxide
Lephoto, M.; Nakano, K.; Appavoo, D.; Owaga, B.; Nozaki, K.; Darkwa, J.
Catalysts 2016, 6, 17. (doi)
(35) Synthesis of Benzofuro- and Indolo[3,2-b]indoles via Palladium-Catalyzed Double N-Arylation and Their Physical Properties
Truong, M. A.; Nakano, K.
J. Org. Chem. 2015, 80, 11566-11572. (doi)
(34) Synthesis and Properties of Benzophospholo[3,2-b]benzofuran Derivatives
Takahashi, M.; Nakano, K.; Nozaki, K.
J. Org. Chem. 2015, 80, 3790-3797. (doi)
Highlighted in Synfacts
(33) Facile Estimation of Catalytic Activity and Selectivities in Co-polymerization of Propylene Oxide with Carbon Dioxide Medi-ated by Metal Complexes with Planer Tetradentate Ligand
Ohkawara, T.; Suzuki, K.; Nakano, K.; Mori, S.; Nozaki, K.
J. Am. Chem. Soc. 2014, 136, 10728-10735. (doi)
(32) Efficient catalyst removal and recycling in copolymerization of epoxides with carbon dioxide via simple liquid-liquid phase separation
Nakano, K.; Fujie, R.; Shintani, R.; Nozaki, K.
Chem. Commun. 2013, 49, 9332-9334. (doi)
(31) Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Iron-Corrole Complexes: Synthesis of a Crystalline Copolymer
Nakano, K.; Kobayashi, K.; Ohkawara, H.; Imoto, H.; Nozaki, K.
J. Am. Chem. Soc. 2013, 135, 8456-8459. (doi)
(30) Facile Synthetic Route to Highly Luminescent Sila[7]helicene
Oyama, H.; Nakano, K.; Harada, T.; Kuroda, R.; Naito, N.; Nobusawa, K. Nozaki, K.
Org. Lett. 2013, 15, 2104-2107. (doi)
Highlighted in Noteworthy Chemistry
(29) λ₅-Phospha[7]helicenes: Synthesis, Properties, and Columnar Aggregation with One-Way Chirality
Nakano, K.; Oyama, H.; Nishimura, Y.; Nakasako, S.; Nozaki, K.
Angew. Chem. Int. Ed. 2012, 50, 695−699. (doi)
(28) Tetravalent Metal Complexes as a New Family of Catalysts for Copolymerization of Epoxides with Carbon Dioxide
Nakano, K.; Kobayashi, K.; Nozaki, K.
J. Am. Chem. Soc. 2011, 133, 10720−10723. (doi)
(27) Stereocomplex of Poly(propylene carbonate): Synthesis of Stereogradient Poly(propylene carbonate) by Regio- and Enantioselective Copolymerization of Propylene Oxide with Carbon Dioxide
Nakano, K.; Hashimoto, S.; Nakamura, M.; Kamada, T.; Nozaki, K.
Angew. Chem. Int. Ed. 2011, 50, 4868−4871.(doi)
selected as VIP, highlighted in Nature Chemistry
(26) New Class of Catalysts for Alternating Copolymerization of Alkylene Oxide and Carbon Dioxide
Okada, A.; Kikuchi, S.; Nakano, K.; Nishioka, K.; Nozaki, K.; Yamada, T.
Chem. Lett. 2010, 39, 1066−1068.(doi)
(25) Bimetallic Mechanism Operating in the Copolymerization of Propylene Oxide with Carbon Dioxide Catalyzed by Cobalt-salen Complexes
Nakano, K.; Hashimoto, S.; Nozaki, K.
Chem. Sci. 2010, 369−373.(doi)
(24) High-Yielding Tandem Hydroformylation/Hydrogenation of a Terminal Olefin to Produce a Linear Alcohol Using a Rh/Ru Dual Catalyst System
Takahashi, K.; Yamashita, M.; Ichihara, T.; Nakano, K.; Nozaki, K.
Angew. Chem. Int. Ed. 2010, 49, 4488−4490.(doi)
selected as an outside cover, highlighted in ChemCatChem
(23) Regioselective Synthesis of Halohydrin Esters from Epoxides: Reaction with Acyl Halides and Rhodium-catalyzed Three-component Coupling Reaction with Alkyl Halides and Carbon Monoxide
Nakano, K.; Kodama, S.; Permana, Y.; Nozaki, K.
Chem. Commun. 2009, 6970−6972.(doi)
(22) Alternating Copolymerization of Cyclohexene Oxide with Carbon Dioxide Catalyzed by (salalen)CrCl Complexes
Nakano, K.; Nakamura, M.; Nozaki, K.
Macromolecules 2009, 42, 6972−6980.(doi)
(21) Synthesis of π-Conjugated Copolymer with Dibenzo[d,d′]benzo[1,2-b:4,5-b′]difuran Unit in the Main Chain
Nakano, K.; Takahashi, M.; Kawaguchi, K.; Nozaki, K.
Synth. Met. 2009, 159, 939−942.(doi)
(20) Tandem Hydroformylation-Hydrogenation of 1-Decene Catalyzed by Rh-Bidentate Bis- (trialkylphosphine)s
Ichihara, T.; Nakano, K.; Katayama, M.; Nozaki, K.
Chem. Asian J. 2008, 3, 1722−1728.(doi)
(19) Carbonylative Polymerization of Oxetanes Initiated by Acetylcobalt Complexes
Permana, Y.; Nakano, K.; Yamashita, M.; Watanabe, D.; Nozaki, K.
Chem. Asian J. 2008, 3, 710−718.(doi)
(18) Synthesis, Structures, and Properties of Unsymmetrical Heteroacenes Containing both Pyrrole and Furan Rings
Kawaguchi, K.; Nakano, K.; Nozaki, K.
Org. Lett. 2008, 10, 1199−1202.(doi)
(17) Synthesis of Sulfur-Rich Polymers: Copolymerization of Episulfide with Carbon Disulfide by Using [PPN]Cl/(salph)Cr(III)Cl System
Nakano, K.; Tatsumi, G.; Nozaki, K.
J. Am. Chem. Soc. 2007, 129, 15116−15117.(doi)
(16) Synthesis of a-Heteroarylpropanoic Acid via Asymmetric Hydroformylation Catalyzed by Rh(I)-(R,S)-BINAPHOS and the Subsequent Oxidation
Tanaka, R.; Nakano, K.; Nozaki, K.
J. Org. Chem. 2007, 72, 8671−8676.(doi)
(15) Regioregular Polymerization of Fluorine-Containing Epoxides
Sakakibara, K.; Nakano, K.; Nozaki, K.
Macromolecules 2007, 40, 6136−6142.(doi)
(14) Synthesis of Ladder-Type π-Conjugated Heteroacenes via Palladium-Catalyzed Double N-Arylation and Intramolecular O-Arylation
Kawaguchi, K.; Nakano, K.; Nozaki, K.
J. Org. Chem. 2007, 72, 5119−5128.(doi)
(13) Selective Formation of Polycarbonate over Cyclic Carbonate: Copolymerization of Epoxides with Carbon Dioxide Catalyzed by Cobalt(III) Complex with Piperidinium End-Capping Arm
Nakano, K.; Kamada, T.; Nozaki, K.
Angew. Chem. Int. Ed. 2006, 45, 7274−7277.(doi)
highlighted in Chemical & Engineering News (2007, Nov. 16, pp 16)
(12) Regio-controlled Ring-opening Polymerization of Perfluoroalkyl-substituted Epoxides
Sakakibara, K.; Nakano, K.; Nozaki, K.
Chem. Commun. 2006, 3334−3336.(doi)
(11) Asymmetric Hydroformylation of Vinylfurans Catalyzed by {(11bS)-4-{[(1R)-2′-Phosphino- [1,1′-binaphthalen]-2-yl]oxy}dinaphtho[2,1-d:1′,2′-f]-[1,3,2]- dioxaphosphepin}rhodium(I) [RhI{(R,S)-binaphos}] Derivatives
Nakano, K.; Tanaka, R.; Nozaki, K.
Helv. Chim. Acta 2006, 89, 1681−1686.(doi)
(10) Alternating Copolymerization of Fluoroalkenes with Carbon Monoxide
Fujita, T.; Nakano, K.; Yamashita, M.; Nozaki, K.
J. Am. Chem. Soc. 2006, 128, 1968−1975.(doi)
(9) Stereospecific Synthesis of Hetero[7]helicenes by Pd-Catalyze Double N-Arylation and Intramolecular O-Arylation
Nakano, K.; Hidehira, Y.; Takahashi, K.; Hiyama, T.; Nozaki, K.
Angew. Chem. Int. Ed. 2005, 44, 7136−7138.(doi)
(8) Asymmetric Amplification in Asymmetric Alternating Copolymerization of Cyclohexene Oxide and Carbon Dioxide
Nakano, K.; Hiyama, T.; Nozaki, K.
Chem. Commun. 2005, 1871−1873.(doi)
(7) Double N-Arylation of Primary Amines: Carbazole Synthesis from 2,2′-Biphenyldiols
Kuwahara, A.; Nakano, K.; Nozaki, K.
J. Org. Chem. 2005, 70, 413−419.(doi) Selected as the most accessed article in 2005
(6) Synthesis of a Polyester Macromonomer via the Cabalt-Catalyzed Alternating Copolymerization of Propylene Oxide and Carbon Monoxide
Nakano, K.; Kondo, F.; Nozaki, K.
J. Polym. Sci. Part A: Polym. Chem. 2004, 42, 4666−4670.(doi)
(5) An Alternative Route to Protected Aldols: Cobalt-catalyzed Hydroformylation of Epoxides and in situ Protection of b-Hydroxyaldehydes by HC(OMe)3
Nakano, K.; Katayama, M.; Ishihara, S.; Hiyama, T.; Nozaki, K.
Synlett 2004, 8, 1367−1370.(doi)
(4) The Double N-arylation of Primary Amines: A New Synthetic Strategy toward Carbazoles with Unique Optical Properties
Nozaki, K.; Takahashi, K.; Nakano, K.; Hiyama, T.; Tang, H. Z.; Fujiki, M.; Yamaguchi, S.; Tamao, K.
Angew. Chem. Int. Ed. 2003, 42, 2051−2053.(doi)
(3) Asymmetric Alternating Copolymerization of Cyclohexene Oxide and CO₂ with Dimeric Zinc Complexes
Nakano, K.; Nozaki, K.; Hiyama, T.
J. Am. Chem. Soc. 2003, 125, 5501−5110.(doi)
(2) Spectral Assignment of Poly[Cyclohexene Oxide-alt-Carbon Dioxide]
Nakano, K.; Nozaki, K.; Hiyama, T.
Macromolecules 2001, 34, 6325−6332.(doi)
(1) Optically Active Polycarbonates: Asymmetric Alternating Copolymerization of Cyclohexene Oxide with Carbon Dioxide
Nozaki, K.; Nakano, K.; Hiyama, T.
J. Am. Chem. Soc. 1999, 121, 11008−11009.(doi)